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Thermodynamics of mixtures Apply thermodynamics to mixtures by defining and finding values for pure species properties, total solution properties, partial molar properties, and property changes of mixing. Explain enthalpy and entropy of mixing in physical terms. Explain how fugacity relates to partial molar Gibbs energy (chemical potential) and.


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1 We have a total of 7 unknowns. 3 in state 1, 3 in state 2, and n, the polytrpoic process exponent. If given any 5 out of these 7, then the remaining 2 can be found. For example, if we know T1, P1, V1, n, P2, then we can find V2, and T2 P V n constant T1 V1 P1 Polytropic process P2 V2 T2 State 1 State 2 P n constant V COMPRESSIONQU ADRANT


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Always true: For cycles: For constant volume (no work done): Work Done Always true: True for constant : True for constant : (PV is constant) True when adiabatic & reversible: (Isentropic) Shaft Work Constant Pressure Constant Volume Perfect, Adiabatic & Reversible (Isentropic) is constant: is constant: is constant: Enthalpy


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